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The Principle of NMR

Potential Energy of a Particle with a Magnetic Moment in a Magnetic Field

summary potential energy Larmor frequency g-factors

A quantum mechanical particle with the spin (no angular momentum) and a charge unequal tozero has a magnetic moment , where is the gyromagnetic ratio.

Within a magnetic field the magnetic moment undergoes a curl free force [1]. Thus it is possible to introduce a potential. In the case of a magnetic field , homogeneous and constant in time, the magnetic moment has the additional potential energy:

where is the spin operator, is the normalised eigenfunction and s3 the corresponding eigenvalue. The spin is quantised i.e. s3 is a discrete value, which leads to a discrete set of possible energy levels.

For example a proton can have two possible spin alignments corresponding to the values s3=. This results in two energy levels which differ by

Bibliography:

  1. Kap. Stationäre Ströme, Magnetostatik In: Lindner, A.: Grundkurs Theoretische Physik, Teubner Studienbücher Physik, 1994, S.202

  summary potential energy Larmor frequency g-factors

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